Thank you everyone for all the help and insight so far.
Looking into this, it seems polycarbonate is a bit of a wimp, but some of its properties are so desirable that it has earned & deserves its place in proper uncompromised [conventional] use.
What I am going to do, & I think if you look into this too that you may agree, but I welcome all feedback - is to use KA's SBR latex primer to treat the OSB and then - new material; apply 1mm thickness of copolymer polypropylene which can be overlapped where necessary and still closely clamped down on to with the final layer of PC.
The PP sheets are much more tolerant of chemicals and as a solid black colour also negates the need for a coloured [bituminous] paint/epoxy resin coating, I do not foresee an issue with this, the respective stabilities of PP & PC aren't affected by being adjacent and the barrier PP provides means I could go further with the OSB treatment, but will [hopefully] not need to....