That's a tricky one. Shooting boards can be accurate...but they're not a silver bullet solution, requiring a fair bit of tuning to get right and constant attention to technique. Furthermore, they tend to be at their best with relatively small pieces that would be dangerous to run across power saws, the bigger the workpiece the more it or the plane tends to "drift" during the shooting board cut.
An alternative might be a "paring block", but you'd have the problem of producing it accurately, still you'd only have to make one and then it's good for lots of subsequent mitres. At the workshops where I trained paring blocks were often used to produce long housing joints with angled walls, and I've experienced just how accurate and clean they can be.
You'd need a straight grained, quarter sawn, dry block of timber about 400mm long (leaving some overhang for easier clamping), 50-75mm thick, and about 100mm wide. Plane one edge at precisely 45 degrees and secure it widthways across your workpiece. Line it up with a knife line or fine pencil line. The workpiece should be roughly finished at approximately 45 degrees, so you're just taking fine parings with the back of the chisel firmly held against the 45 degree slope on the paring block.