Never heard of the term 'cold toes' but I ain't a welder.
For fear it all might sound daunting for a newbie, making stuff from angle iron, I hope ye will grant me a licence to waffle a bit.
Thankfully cold toes are not really an issue with arc welding for what most need regarding workshop stuff like machine bases,
(most aren't using machines that weigh over a tonne)
And you can grind nice deep bevels in most cases and build up a good pool.
Were not building the Titanic, welding inch thick steel in stressful situations.
5mm thick angle iron is pretty stout.
Strange picture underneath of red hot metal to illustrate adequate penetration from this wee Lidl job.
Treat the puddle as custard and orient the work so gravity works in your favour.
Best practice if possible, no need to do vertical welds unless you're working on
something that cannot be disassembled, like tractors for instance.
And if in doubt grind it all back and start again, not an issue as most here are woodworkers, not price work welders who get a wasted rod or extra time taken out of their pay packet
And make a few picks from long masonry nails for removing any slag grit, as
if you can hear the grit, you can't weld on it.
This is important when joining up those good tacks that one might make,
before blasting it with a long bead to make it really skookum as frig, and not a wee measly tack like on many factory made things.
Tacks often required in different locations to counter the pull of the last good tack.
And wear goggles for the entire duration (yes under the shield/mask) and afterwards, until you can touch the metal with your hand, as it can act like water on oil and spit at you when you're cooking sausages.
Goggles kept on anyway for cleaning up with grinder, or finding slag with the pick that can ricochet at your eyes/teeth.
A bench grinder is handy to have for various picks, keeping one handled awl sharp, and for another nail or two that you hit with an tack hammer.
I fear that even I've made it sound complicated
I'm not the best at being straight to the point.
Good luck
Tom