Hi Jake
The big trouble with polystyrene is that it burns very hot and the smoke and fumes from it are toxic. It melts and spreads while it burns and the heat it gives off is extreme. If there is an air gap around or above it the effect is even worse and the flame propogation is much quicker.
When polystyrene tiles were really popular, in the 70s and early 80s people used to ignore the fixing advice and use blobs of glue to install them on their ceilings. The air gap, though small, behind the tiles was enough to spread fire at an almost unbelievable rate. I have seen fire travel the line of a poly "picture rail" around a room faster than it could be followed!
The cyanide and stuff that it gives off make the smoke highly dangerous. It is said that one good breath of the stuff will knock you out and the second will kill you. This is why we have always been very wary of the product in all its forms.
As to the temperature in a fire situation - 600 degrees C at ceiling height could easily be increased to 1000 degrees C when this stuff is in the room. At those sorts of temperatures the chance of flashover, where everything in the room self-ignites, is high. The backdraught potential is even better - where the temperature is raised enough to mean that any inrush of air will lead to super expansion of the gases and create a smoke explosion. Once the cover for it is broken or burned away, melted or whatever, the fire can race away. Way past time to be getting out!
This is why I actually hate expanded polystyrene! It can be bad for your health in a major way.
It is a marvellous material but people do not understand its bad points. For me they mostly outweigh the good points.
Horrible stuff!!
Cheers.
SF