In my first mini-thesis on steels used in woodworking tools, I mentioned that several 'other' grades of steel have been used in tool making over the years. Given that they crop up from time to time, I thought I'd mention a couple I've come across.
The first is SILVER STEEL. During the second half of the 19th century, quite a few experiments were made adding alloying elements to steel, some more successful than others. One result of this experimentation was a straight carbon steel with a very small proportion of Chromium added. This had some benefits to heat treatment, but also gave the finished steel a more silvery appearance when polished up. It was taken up by several saw makers, and their etches sometimes contain the words 'silver steel' - Tyzack Sons and Turner were one such user, and they used it for many, many years. I have two Tyzack saws I bought new in the 1980s, and one of them is so marked.
Silver steel also came to be marketed in the form of drawn or ground rods (usually round, sometimes square) accurate to diametrical dimension, and about 13" long, in many sizes from very small to 2" (50mm) diameter. This can still be bought from engineer's merchants (it's known as 'drill rod' in North America, which reveals one of it's intended purposes), and is a fine starting point for anybody wanting to make their own tools. It's supplied in the annealed condition, and can be worked fairly easily, though it's much harder than mild steel! It hardens and tempers in water, and is about as close to 'straight' carbon steel as anything currently easily commercially available. It has it's own British Standard - BS1407 of 1970, which states that it shall contain Carbon 1.1 - 1.2%, Silicon 0.1 - 0.25%, Manganese 0.3 - 0.4% and Chromium 0.4 - 0.5%. I assume that the North American spec. is very similar.
The second is BALL BEARING STEEL. This is quite similar to silver steel, but has Carbon 0.95 - 1.1%, Manganese 0.4 - 0.7%, and Chromium 1.2 - 1.6%. In the UK, it is known as EN31 or 535/A99 (the British Standards Institution keep changing the way the specify steels - very confusing!), and in America as AISI/SAE 52100. This one has been around for a long time, it's major use being for the making of rolling element bearings. The chromium content helps it get a bit harder than straight carbon steel, and gives a deeper hard case. In days gone by, people used to use old bearing races to make such things as engineer's scrapers, since the steel could be annealed, worked, hardened and tempered pretty well exactly the same as straight carbon steel (not so wise these days - many other grades of steel are used to make rolling element bearings now, and some of these won't respond to simple heat treatments). Some tool makers adopted it, it's most recent use being by Stanley in their recent Sweetheart socket chisel range.
The third is SPRING STEEL. There are several grades, the ones most used these days being (UK) CS80 and CS95 - the North American exact equivalents being AISI/SAE 1080 and 1095. Most often used in saw making, these are also pretty close to being straight carbon steels, with only small additions of silicon. They are useful to tool makers because they respond to oil hardening, which is a slower process than water hardening and thus less likely to case internal stresses in the finished item. These steels have also been used in heavier blades - I gather that Robert Sorby use a spring steel for their long, thin paring chisels. I've had a couple of these for years, and can confirm that the steel is quite similar to O1 in the way it behaves; the chisels also have a slight degree of flexibility that makes them quite sensitive to use for fine paring.
Lastly, I'll just mention water-hardening steels, grades W1 and W2, which do get mentioned from time to time. These are effectively the grade designations of straight carbon steel of 1% carbon, having virtually no alloying elements added (W1 has 0.2% Silicon, W2 has the same plus 0.2% vanadium). They are virtually unobtainable commercially, since every practical use they ever had is better served by other steels, the sole exception being custom blade-making. The nearest available equivalents are the Japanese blade steels, sometimes called 'white steel' and 'blue steel'. They are about the nearest to the old Sheffield 'cast steel' still available.
Hope that's not 'too much information' - thought it might answer a few questions for a few readers when some of the regular posters start spraying specification numbers around!