Sodium hydroxide is available inexpensively over-the-counter in your local ironmongers' shop as "caustic soda", used mainly for drain cleaning.
I recently tried to get hydrogen peroxide from Boots, but they only keep it in very small bottles for medicinal purposes (cleaning/disinfecting wounds, NOT drinking!), or, with unwanted additives, as hair bleach. This is frustrating, as it's generally nicer to use than the chlorine bleach you buy in the supermarket. Apparently you can get larger quantities and higher concentrations from specialist suppliers.
Both peroxide and NaOH (sodium hydroxide) are nasty, but on balance (and it's a tough call), caustic soda is probably nastiest of all. Wear eye protection, long rubber gloves (i.e. must be waterproof) and a good apron if you don't want holes in clothes (or worse, chemical burns).
And always add crystals to water to dissolve, never the other way round (wrong way means it spits back!).
Don't ever mix the two, either directly or by treating wood with the second one without washing the wood very well first with water. The direct reaction between them is likely to be rather "energetic" (not in a good way).
Aside: if you know anybody who works in rocketry, that might be handy: HTP ("High-Test Peroxide") is the oxidiser in many propulsion systems, including the Nammo rockets in the Bloodhound car, and quite a lot of the current crop of space launch vehicles. HTP is very concentrated peroxide and extremely nasty stuff to handle. You could probably bleach half a forest with the contents of Bloodhound's oxidiser tank!
There's at least one chemist on this forum, so I'm happy to be corrected...
E.