Thanks everyone for taking the time to reply. I realise my question could have been better worded. I do indeed intend to float a fresh concrete floor on top of the existing pad, which has been in existence for at least 60 years. It was not expertly laid originally, not being perfectly flat and level, but was crudely overbuilt and has stood the test of time until now and I'm confident it will suffice for my project.
My query really centred around whether a waterproof membrane simply laid on the existing pad would be good enough or whether it would need elevating first in order to resist the wet. The first reply by Lons seems to have answered this and I can imagine the only tricky part is dealing with the corners where the DPC sheet would have to be folded in a sort of 'bed sheet corners'. Or maybe cut and patched?
My alternative thoughts had focussed on shuttering the entire new floor area to a minimum necessary to achieve a level rectangle - probably about 30 to 50 mm deep ( I don't yet know what amount of fall the existing pad has) then concreting to the top of this shuttering so as to easily be able to use a scraper bar to fill to level. Then a DPC covering the whole thing and build on a wooden sole plate as usual.
My hesitation with this idea is: would the loadbearing edges be strong enough if some parts of the 'table' were pretty thin?
Jameshow's suggestion attracts for not having to lay bricks but I'm not too keen on a wooden sole plate so low down - but combined with Jacob's plastic beams (which I was unaware of) might be the way to go.
Lots of food for thought and research. Thanks for the responses.