I've done quite a bit of laminating and there are a couple of things you need to bear in mind before you laminate onto ply. you need to follow this list and you should get a decent result.
1. Acetone wipe the ply you will be laminating onto. Some ply has an oily surface that can lead to the GRP cap popping off and the acetone should remove most of it giving it better adhesion.
2. Prime the surface of the ply with the resin, this will also improve the adhesion and it will soak up quite a bit of resin, you don't have to wait for it to dry before you start laminating onto it.
3. For most Polyesters you use a 2.5 to 1 ratio of Resin to Glass weight, so a meter square piece of 450 gram chopped strand matt will use upto 1125 grams of resin. If you want to pigment the resin then you dont really want to use more than about 4% of the total resin weight of pigment in a laminating resin.
4. Paint Polyester resin onto the ply, leaving the surface wet with a decent layer of catalysed resin, then push the CSM (Chopped Strand Mat) into this resin, then paint on the resin onto the top of the CSM, the binder on the mat can take a while to soften so its best to wet it out as fast as possible. You then go over the wet CSM quickly in a "stippling" action to help the binder break down and drive some of the air out.
You then have to use a consolidation roller to compact the glass down and drive the trapped air out of the laminate, we recommend a fin roller for as it's better for driving air to the surface.
Until you are used to doing this I would not recommend laminating more than 1 layer at a time till you get the feel for it.
5. If your going to use a surface tissue you want anywhere between 5:1 up to 10:1 Resin to glass ration depending on the tissue type.
6. If you are going to paint a flowcoat on you want to use 450-600 G/m2 of flowcoat to achieve the correct thickness. An alternative to buying a specialist flowcoat you can use a standard polyester Gelcoat with 2% of a wax solution (Solution MW is the Scott Bader Manufacture) added to it by weight and mixed in well before the addition of catalyst. Make sure you get one that is suitable for exterior applications.
You probably will not be able to paint straight onto a flowcoated surface because the wax that stops air inhibition will stop the paint from sticking, you can however abrade the wax off with wet and dry and you should be able to paint onto the abraded surface after giving it an acetone wipe, but to be honest I would not recommend it as it never really looks as good or wears as well as a flowcoated surface.
Heres a couple of links to the sort of products you want to be using and a link to one of Scotts distributors which would give you an idea about the prices you will pay. Unfortunately Scotts no longer deal with cash sales
http://www.scottbader.com Resin manufacturers website
http://www.fiberglasssupplies.co.uk/ On of Scotts Distributors
Laminating resin
http://www.scottbader.com/downloads/UK_PDF_Datasheet_Files/Resins & Compounds/2-8500PA - Mar 01.pdf
Flowcoat
http://www.scottbader.com/downloads/UK_PDF_Datasheet_Files/Gelcoats/Topcoat 65PAX - nov07.pdf
Finally the type of roller you need to use to consolidate the laminate, clean it with acetone thoroughly after use or they start to seize up
http://www.fiberglasssupplies.co.uk/acatalog/Fin_Rollers.html
Sorry for the small edition of War and Peace, it's not really as hard as it sounds