@Eshmiel: There are various bits of info about the interweb about how to chemically sharpen metal files. As I recall, you dip them in some kind of weak acid for a length of time - until the acid eats enough metal from each blunt serration such that it again comes to a point.
AES: Yup, there are various such pieces of info to find. I've not tried myself, but I suspect that in the case of file worn as much as Disco_Monkey 79's (the OP), the results are very unlikely to be successful. Any type of acid treatment can "only" take away from what's already there (be it general crud, or, to a small extent, the base metal). Acid cannot "add" anything, especially not new, "pointed" teeth IMO, so if the OP's file really is as worn as he says, then I suspect it's finished - as a file. But I haven't ever tried this method myself, and apparently, there's at least one company in the US that does do this. But again, I can't myself see that acid can add to what is really already missing.
I have a couple of very old worn files which my Dad (died 1977) turned into bearing, etc scrapers when he was working, and very effect they are too, even today. Though the number of times I actually need a scraper are very few and far between these days (scraping in new white metal bearings for your Ford 100E crankshaft has gone out of fashion you know)!!
Though there ARE other uses for metal scrapers - sometimes.
Apart from scrapers (metal), I know of no other "certain" uses for old files. But there have been posts here in the past about "turning" them into wood turners tools (sorry for the pun)! Some say it should work, others think "too brittle". I'm not a wood turner myself so I just dunno, sorry.
But IF he's still around, member CHJ not only has a very good engineering (metal) apprenticeship background but is also a very accomplished wood turner. If he doesn't pop up here soon I suggest PM-ing him (sorry, "conversation"-ing) him.
HTH
Edit for P.S. Clearly my post (above) has crossed with a couple of others. Myself I just do not know if files turned into turning tools are too brittle or not, sorry. What I can definitely say is that files (good ones anyway) are about the hardest bits of metal you're ever likely to find in the average workshop. Hardness does of course also mean "brittle" but if that brittleness equals a definite safety hazard in the wood turning use I just do not know, sorry.