Jacob":2jcwnelk said:NOT plastic (shatters)
Point of order, but while I'd agree that something like MDF is probably consistently safe, not all plastics shatter. Some do, some don't - it depends very much on the particular plastic.
I seem to recall there was a discussion about table saw guards on this very forum a while back that was discussing this, suggesting polycarbonate/lexan for this very property of not shattering. Certainly the only table-saw kickback incident I've ever had was with a bit of polycarbonate (grazed my knuckles and nothing else, thankfully) and it didn't shatter at all, just got chewed up in the parts that the saw blade hit. From that experience I'd be as comfortable using a polycarbonate push-stick as an MDF one... but I'd do my research before I tried it and then use MDF anyway 'cause polycarbonate is far more expensive.
Off the top of my head, I think acrylic and ABS can shatter relatively easily, so I wouldn't want a push-stick made out of those. I'd be pretty surprised if polyethylene/HDPE did, so I'd expect it'd probably be safe enough to make pushsticks out of those thick white plastic cutting boards you can pick up for cheap in supermarkets. I can't think of a reason past "not full of formaldehyde" that you'd want to use one in preference to MDF, though.