Most acids work most of the time.
The commercial stuff is usually (but not always) formic acid, as used by Ants when they bite you. It's not poisonous, which is one reason why it's used.
Most of the removers will damage chrome or other kinds of plating, so you do need to keep an eye on progress. They also work better if the solution is warm and/or you wipe over the surface, to provide a supply of fresh acid and clear away the removed was-limescale.
It is worth doing regularly, as limescale itself also attacks chrome plating.
We live in a hard water area, and down the years it has done a lot of damage to our kitchen taps and bathroom fittings. I struggle to keep up with it. Basic rule is make sure all the tap washers are good and the taps don't drip. Ceramic cartridges are a right PITA when they begin to wear, as there are so many variations on the designs.
Just in case you are wondering...
I bought (but never fitted) an ion exchange softener for the whole house at one point, but that had issues. There several main brands, actually all owned by one company, who pretty much have the market sewn up in the UK. Build quality and throughput were rubbish, and I couldn't find anywhere to install it neatly either. Idiotic and expensive impulse buy. They do work, incidentally (there is one in every dishwasher), but there is a very limited range made to do whole houses. I probably should have looked at small commercial/industrial ones. The magnetic ones and "catalytic" ones seem to be snake oil.