I should have and forgot to mention that I have installed 100mm of PIR boards in between the joists. When we had the extension done, an "error" was made and they had to redo the wall insulation. As a result I had a lot of the 100mm PIR foam in various sizes left over, I've only managed about 1/3-1/2 of the ceiling with complete boards and the rest made up of pieces which was a PITA. I'm going to foam the gaps - not looking forward to that.
My thought on the 10mm was really around an extra layer of thermal decoupling between the finished ceiling and the joists.
So basically, I'm understanding that everyone is saying that doing this is a) pointless and b) dangerous in the event of fire when used internally. Thanks for the advice.
Moving on from that, what would be a suggested covering? I'm on my own so 8x4's of anything is going to be "fun" (unless I get hold of a suitable sheet lifter).
Thanks again all.