Hi
I am a fan of Cascamite and use it for all large glue-ups.
I have never used the volume method and always weigh out the powder and water.
I use a small set of electronic scales and 4 little plastic pots including one to mix the glue in.
1. Rinse out 3 of the pots but don't dry them - this way you have already allowed for the small loss of liquid that arises when you transfer from one pot to another (the mixing of Cascamite is very sensitive to changes in quantities).
2. Weigh out x grammes of powder in the dry pot - it takes a bit of experience to judge how much but in my experience (!) it is infinitely preferable to do too much rather than not enough as it is a real hassle to make up more if you run out in the middle (actually invariably at the sweaty point) of a big glue-up. I usually note on the tub what quantity I used for a job, so I can use it as a future reference point.
3. Weigh x/2 grammes of water - this gives the required quantity, but I usually add another gramme (to say 50g of water) as I prefer a slightly more runny mix.
4. Weigh half of the water into the mixing pot - actually it is better to make it just over half by a gramme or so.
5. Add all of the powder to this and mix with a stick. At first it will seem like it is far too much powder for this amount of water, but after a minut or so, it will convert to a smooth thick consistency. Ensure that it is quite smooth and all small lumps have been absorbed.
6. Add the remaining half of the water and stir in until is is all the same consistency, which should be fairly runny.
I usually apply this glue with a stiff brush either a glue brush or if it is a door glue-up with big tenons, I use an old 1/2" paint brush.
As to working time, I would comfortably expect it to be workable for an hour, but three hours would only be achievable if it was very cold I would think.
Clean up is best with hot (tap) water and some washing up liquid.
Hope that helps and better luck next time.
There was an article in F&C this or last month which has a good summary of glues - I have yet to read it properly.
Cheers
Scholar