I've tried this and it works a treat. Rusty old iron nails in a jar of water for a few days. New steel nails are not so effective. Buy a brand of black tea leaves (not teabags). When you've got a nice rusty juice in your jar, mash a strong brew of the tea, when cool paint your pine with the tea and while still damp, give a coating of the rusty nail juice. The Ferrous oxide reacts with the tannin in the tea and goes a dark colour. Allow to dry. If you want it darker, repeat the process. I did 3 coats and the piece went as black as our fire back.